His two lay books, Fooled By Randomness and The Black Swan, are only samples of his work. If you want to judge him, read his technical book Dynamic Hedging, and his published papers, starting at SSRN.com:
http://papers.ssrn.com/so
His website also has a section on his scholarly work as well:
http://fooledbyrandomness
Regarding his credibility in academia, besides Terry Tao's informal endorsement (or whatever you consider Terry's static sidebar link to Taleb's main non-book work to be), the late Berkeley statisticia